Nucleophilic Carbene Catalyzed Synthesis of 1,2 Amino Alcohols Via Azidation of Epoxy Aldehydes

Nickel-Catalyzed Reductive Carboxylation of Styrenes Using CO2

Catalytic Asymmetric Intermolecular Stetter Reaction of Glyoxamides with Alkylidenemalonates

Catalytic Asymmetric Stetter Reaction Onto Vinylphosphine Oxides and Vinylphosphonates

Scope of the Asymmetric Intramolecular Stetter Reaction Catalyzed by Chiral Nucleophilic Triazolinylidene Carbenes

Enantioselective Synthesis of Indolizidines Bearing Quaternary Substituted Stereocenters via Rhodium-Catalyzed [2 + 2 + 2] Cycloaddition of Alkenyl Isocyanates and Terminal Alkynes

Asymmetric Synthesis of Bicyclic Amidines via Rhodium-Catalyzed [2+2+2] Cycloaddition of Carbodiimides

Enantioselective Cross-Coupling of Anhydrides with Organozinc Reagents: The Controlled Formation of Carbon-Carbon Bonds through the Nucleophilic Interception of Metalacycles

A Diastereoselective Ring Contraction of 1,3-Dioxepins to 2,3,4-Trisubstituted and Tetrasubstituted Tetrahydrofurans

Development of Chiral Bicyclic Triazolium Salt Organic Catalysts: The Importance of the N-Aryl Substituent

A Rapid Total Synthesis of (+/-)-Sylvone

More than Bystanders: The Effect of Olefins on Transition-Metal-Catalyzed Cross-Coupling Reactions

Towards the total synthesis of FD-838: modular enantioselective assembly of the core

The [1,3] O-to-C rearrangement: opportunities for stereoselective synthesis

Alkene-Directed Regioselective Nickel-Catalyzed Cross-Coupling of Cyclic Anhydrides with Diorganozinc Reagents

Rhodium-Catalyzed Enantioselective Desymmetrization of meso-3,5-Dimethyl Glutaric Anhydride: A General Strategy to syn-Deoxypolypropionate Synthons

A Concise Synthesis of Eupomatilones 4, 6, and 7 by Rhodium-Catalyzed Enantioselective Desymmetrization of Cyclic meso Anhydrides with Organozinc Reagents Generated In Situ

Nucleophilic Carbene and HOAt Relay Catalysis in an Amide Bond Coupling:? An Orthogonal Peptide Bond Forming Reaction

A Diastereoselective Intermolecular Heck Reaction of 1,3-Dioxepins

Ligand-Dependent Catalytic Cycle and Role of Styrene in Nickel-Catalyzed Anhydride Cross-Coupling: Evidence for Turnover-Limiting Reductive Elimination

Enantioselective Synthesis of Hydrobenzofuranones Using an Asymmetric Desymmetrizing Intramolecular Stetter Reaction of Cyclohexadienones

A modular approach to the synthesis of 2,3,4-trisubstituted tetrahydrofurans

Selective Substituent Transfer from Mixed Zinc Reagents in Ni-Catalyzed Anhydride Alkylation

Enantioselective formation of quaternary stereocenters using the catalytic intramolecular Stetter reaction

Surveying approaches to the formation of carbon-carbon bonds between a pyran and an adjacent ring

Rhodium-Catalyzed [2 + 2 + 2] Cycloaddition of Alkenyl Isocyanates and Alkynes

Asymmetric Synthesis of Hydrobenzofuranones via Desymmetrization of Cyclohexadienones Using the Intramolecular Stetter Reaction

Enantioselective Rhodium-Catalyzed [2+2+2] Cycloaddition of Alkenyl Isocyanates and Terminal Alkynes: Application to the Total Synthesis of (+)-Lasubine II

A Sakurai-Prins-Ritter Sequence for the Three-Component Diastereoselective Synthesis of 4-Amino Tetrahydropyrans

A highly enantio- and diastereoselective catalytic intramolecular stetter reaction

An efficient synthesis of achiral and chiral 1,2,4-triazolium salts: Bench stable precursors for N-heterocyclic carbenes

The effect of pre-existing stereocenters in the intramolecular asymmetric Stetter reaction

Enantioselective protonation of catalytically generated chiral enolates as an approach to the synthesis of alpha-chloroesters

Highly efficient nickel-catalyzed cross-coupling of succinic and glutaric anhydrides with organozinc reagents

Regioselective Lewis acid-mediated [1,3] rearrangement of allylvinyl ethers

Stereoselective Lewis acid mediated [1,3] ring contraction of 2,5-dihydrooxepins as a route to polysubstituted cyclopentenes

Complementary diastereoselective reduction of cyclic gamma-keto acids: Efficient access to trisubsituted gamma-lactones

Use of acid fluorides increases the scope of the reductive acylation of esters

Enantioselective synthesis of quaternary stereocenters via a catalytic asymmetric Stetter reaction

A palladium-catalyzed enantioselective alkylative desymmetrization of meso-succinic anhydrides

Conversion of alpha-haloaldehydes into acylating agents by an internal redox reaction catalyzed by nucleophilic carbenes

A unique catalyst effects the rapid room-temperature cross-coupling of organozinc reagents with carboxylic acid fluorides, chlorides, anhydrides, and thioesters

Decarbonylative cross-coupling of cyclic anhydrides: Introducing stereochemistry at an sp(3) carbon in the cross-coupling event

Effect of the Michael acceptor in the asymmetric intramolecular Stetter reaction

1,3-polyol arrays via the stereoselective rearrangement of vinyl acetals

Stereoretentive O-to-C rearrangement of vinyl acetals: Solvent cage effects as a stereocontrol element

A highly enantioselective catalytic intramolecular Stetter reaction

A mild and efficient catalytic alkylative monofunctionalization of cyclic anhydrides