Photoredox-Catalyzed Generation of Tertiary Anions from Primary Amines via a Radical Polar Crossover

Photocatalytic Activation of Aryl(trifluoromethyl) Diazos to Carbenes for High-Resolution Protein Labeling with Red Light

Rhodium(III)-Catalyzed Remote Hydroamidation of Internal Alkenes Via Chain Walking

Late-Stage Isotopic Exchange of Primary Amines

Orange Light-Driven C(sp2)–C(sp3) Cross-Coupling via Spin-Forbidden Ir(III) Metallaphotoredox Catalysis

Electrochemically Controlled Ruthenium-Catalyzed Olefin
Metathesis

Alkane Solvent-Derived Acylation Reaction Driven by Electric Fields

Dynamic crosslinking compatibilizes immiscible mixed plastics

Deep Red to Near-Infrared Light-Controlled Ruthenium-Catalyzed Olefin Metathesis

Photoinduced Nickel-Catalyzed Selective N-Demethylation of Trialkylamines Using C(sp2)–Bromides as HAT Reagents

Coupling of alpha-bromoamides and unactivated alkenes to form gamma-lactams through EDA and
photocatalysis

Modular Synthesis of Unnatural Peptides via Rh(III)-Catalyzed Diastereoselective Three-Component Carboamidation Reaction

Overcoming Photochemical Limitations in Metallaphotoredox Catalysis: Red-Light-Driven C–N Cross-Coupling

Rhodium(III)-Catalyzed Anti-Markovnikov Hydroamidation of Unactivated Alkenes Using Dioxazolones as Amidating Reagents

Targeted activation in localized protein environments via deep red photoredox catalysis

Tuning through-space interactions via the secondary coordination sphere of an artificial metalloenzyme leads to enhanced Rh(III)-catalysis

Rh(III)-Catalyzed Intra- and Intermolecular 3,4-Difunctionalization of 1,3-Dienes via Rh(III)-π-Allyl Amidation with 1,4,2-Dioxazolones

Development of optimized drug-like small molecule inhibitors of the SARS-CoV-2 3CL protease for treatment of COVID-19

Tuning the Electrochemical and Photophysical Properties of Osmium-Based Photoredox Catalysts

Photocatalyzed Triplet Sensitization of Oximes Using Visible Light Provides a Route to Nonclassical Beckmann Rearrangement Products

Photons or Electrons? A Critical Comparison of Electrochemistry and Photoredox Catalysis for Organic Synthesis

Dual Nickel/Photoredox-Catalyzed Deaminative Cross-Coupling of Sterically Hindered Primary Amines

Site-Selective α-C–H Functionalization of Trialkylamines via Reversible Hydrogen Atom Transfer Catalysis

Diastereoselective Three-Component 3,4-Amino Oxygenation of 1,3-Dienes Catalyzed by a Cationic Heptamethylindenyl Rhodium(III) Complex

Late-Stage N-Me Selective Arylation of Trialkylamines Enabled by Ni/Photoredox Dual Catalysis

Rh(III)-Catalyzed Three-Component Syn-Carboamination of Alkenes Using Arylboronic Acids and Dioxazolones

Iron-Catalyzed Photoinduced LMCT: A 1° C–H Abstraction Enables Skeletal Rearrangements and C(sp3)–H Alkylation

Iron-Catalyzed C(sp3)–H Alkylation through Ligand-to-Metal Charge Transfer

Copper Catalyzed C(sp3)–H Bond Alkylation via Photoinduced Ligand-to-Metal Charge Transfer

Development of a Platform for Near-Infrared Photoredox Catalysis

Photoredox-Catalyzed Deaminative Alkylation via C–N Bond Activation of Primary Amines

A site-selective amination catalyst discriminates between nearly identical C–H bonds of unsymmetrical disubstituted alkenes

Direct Regio‐ and Diastereoselective Synthesis of δ ‐Lactams from Acrylamides and Unactivated Alkenes Initiated by Rh(III)‐Catalyzed C−H Activation

Synthesis of Sterically Hindered Primary Amines by Concurrent Tandem Photoredox Catalysis

Electrochemical Synthesis of Hindered Primary and Secondary Amines via Proton-Coupled Electron Transfer

Rhodium(III)-Catalyzed Three-Component 1,2-Diamination of Unactivated Terminal Alkenes

Regioselective Alkylative Cross-Coupling of Remote Unactivated C(sp3)–H Bonds

A Rh(III)-Catalyzed Formal [4+1] Approach to Pyrrolidines from Unactivated Terminal Alkenes and Nitrene Sources

Rhodium(III)-Catalyzed Cyclopropanation of Unactivated Olefins Initiated by C–H Activation

Ligand Controlled Ir-Catalyzed Regiodivergent Oxyamination of Unactivated Alkenes

Rh(III)-Catalyzed C-H Activation-Initiated Directed Cyclopropanation of Allylic Alcohols

Visible-Light-Controlled Ruthenium-Catalyzed Olefin Metathesis

Asymmetric delta-Lactam Synthesis with a Monomeric Streptavidin Artificial Metalloenzyme

Photoredox Catalyzed Site Selective alpha-C(sp3)-H Alkylation of Primary Amine Derivatives

Ir-Catalyzed Intermolecular Branch-Selective Allylic C-H Amidation of Unactivated Terminal Olefins

Photoredox catalysis using infrared light via triplet fusion upconversion

Photoinduced Ligand-to-Metal Charge Transfer Enables Photocatalyst-Independent Light-Gated Activation of Co(II)

The Catalytic Alkylative Desymmetrization of Anhydrides in a Formal Synthesis of Ionomycin

Generation of Phosphoranyl Radicals via Photoredox Catalysis Enables Voltage-Independent Activation of Strong C-O Bonds

Direct alpha-alkylation of primary aliphatic amines enabled by CO2 and electrostatics

Stereodivergent Rhodium(III)-Catalyzed cis-Cyclopropanation Enabled by Multivariate Optimization

External Regulation of Cobalt-Catalyzed Cycloaddition Polymerization with Visible Light

Ir(III)-Catalyzed Carbocarbation of Alkynes through Undirected Double C-H Bond Activation of Anisoles

Electronic and Steric Tuning of a Prototypical Piano Stool Complex: Rh(III) Catalysis for C-H Functionalization

Complementary Strategies for Directed C(sp3)-H Functionalization: A Comparison of Transition-Metal-Catalyzed Activation, Hydrogen Atom Transfer, and Carbene/Nitrene Transfer

Cluster Preface: Alkene Halofunctionalization

Regiodivergent Iridium(III)-Catalyzed Diamination of Alkenyl Amides with Secondary Amines: Complementary Access to gamma- or delta-Lactams

Rhodium-Catalyzed Desymmetrization of meso-Glutaric Anhydrides to Access Enantioenriched anti,anti-Polypropionates

A Mild Hydroaminoalkylation of Conjugated Dienes Using a Unified Cobalt and Photoredox Catalytic System

Experimental and Computational Gas Phase Acidities of Conjugate Acids of Triazolylidene Carbenes: Rationalizing Subtle Electronic Effects

Directed gamma-C(sp3)-H Alkylation of Carboxylic Acid Derivatives through Visible Light Photoredox Catalysis

Enantioselective N-heterocyclic carbene-catalyzed nucleophilic dearomatization of alkyl pyridiniums

Cluster Preface: Catalytic Aerobic Oxidations

A Photochemical Two-Step Formal [5+2] Cycloaddition: A Condensation-Ring-Expansion Approach to Substituted Azepanes

Dual Nickel- and Photoredox-Catalyzed Enantioselective Desymmetrization of Cyclic meso-Anhydrides

Correlating Reactivity and Selectivity to Cyclopentadienyl Ligand Properties in Rh(III)-Catalyzed C-H Activation Reactions: An Experimental and Computational Study

Heptamethylindenyl (Ind*) enables diastereoselective benzamidation of cyclopropenes via Rh(III)-catalyzed C-H activation

N-Heterocyclic Carbene and Chiral Bronsted Acid Cooperative Catalysis for a Highly Enantioselective [4+2] Annulation

Amide-directed photoredox-catalysed C-C bond formation at unactivated sp3 C-H bonds

Visible Light-Gated Cobalt Catalysis for a Spatially and Temporally Resolved [2+2+2] Cycloaddition

Rhodium-catalysed syn-carboamination of alkenes via a transient directing group

Rhodium(III)-Catalyzed Allylic C(sp3)-H Activation of Alkenyl Sulfonamides: Unexpected Formation of Azabicycles

Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes

Oxidatively Initiated NHC-Catalyzed Enantioselective Synthesis of 3,4-Disubstituted Cyclopentanones from Enals

Organic chemistry: Natural polarity inverted

Expedient Access to 2,3-Dihydropyridines from Unsaturated Oximes by Rh(III)-Catalyzed C-H Activation

Influence of Electronic Effects on the Reactivity of Triazolylidene-Boryl Radicals: Consequences for the use of N-Heterocyclic Carbene Boranes in Organic and Polymer Synthesis

Rhodium(III)-Catalyzed C-H Activation: An Oxidative Intramolecular Heck-Type Reaction Directed by a Carboxylate

Zn-Catalyzed Enantio- and Diastereoselective Formal [4 + 2] Cycloaddition Involving Two Electron-Deficient Partners: Asymmetric Synthesis of Piperidines from 1-Azadienes and Nitro-Alkenes

Cluster Preface: Catalysis Using Sustainable Metals - Part II

Enantioselective Rhodium-Catalyzed Isomerization of 4-Iminocrotonates: Asymmetric Synthesis of a Unique Chiral Synthon

Ligand design for Rh(III)-catalyzed C-H activation: an unsymmetrical cyclopentadienyl group enables a regioselective synthesis of dihydroisoquinolones

Rh(I)-Bisphosphine-Catalyzed Asymmetric, Intermolecular Hydroheteroarylation of alpha-Substituted Acrylate Derivatives

Catalysis Using Sustainable Metals - Part I

Enantioselective N-Heterocyclic Carbene-Catalyzed beta-Hydroxylation of Enals Using Nitroarenes: An Atom Transfer Reaction That Proceeds via Single Electron Transfer

Rh(III)-Catalyzed Cyclopropanation Initiated by C-H Activation: Ligand Development Enables a Diastereoselective [2 + 1] Annulation of N-Enoxyphthalimides and Alkenes

Stereoelectronic Basis for the Kinetic Resolution of N-Heterocycles with Chiral Acylating Reagents

Cobaltate Anion Couples Terminal Dienes with Trifluoroacetic Anhydride: A Direct Fluoroacylation of 1,3-Diene

A Late-Stage Strategy for the Functionalization of Triazolium-Based NHC Catalysts

Rapid Construction of (-)-Paroxetine and (-)-Femoxetine via an N-Heterocylic Carbene Catalyzed Homoenolate Addition to Nitroalkanes

Stereoselective Synthesis of Dioxolanes and Oxazolidines via a Desymmetrization Acetalization/Michael Cascade

Rh(III)-Catalyzed Decarboxylative Coupling of Acrylic Acids with Unsaturated Oxime Esters: Carboxylic Acids Serve as Traceless Activators