Rhodium(III)-Catalyzed Intramolecular Hydroarylation, Amidoarylation, and Heck-type Reaction: Three Distinct Pathways Determined by an Amide Directing Group

Rhodium(III)-Catalyzed C-H Activation Mediated Synthesis of Isoquinolones from Amides and Cyclopropenes

SNAr-Derived Decomposition By-products Involving Pentafluorophenyl Triazolium Carbenes

Asymmetric N-Heterocyclic Carbene Catalyzed Addition of Enals to Nitroalkenes: Controlling Stereochemistry via the Homoenolate Reactivity Pathway To Access delta-Lactams

Catalytic, Asymmetric Indolizidinone Aza-Quaternary Stereocenter Synthesis: Expedient Synthesis of the Cylindricine Alkaloid Core

A Catalytic Asymmetric Synthesis of Polysubstituted Piperidines Using a Rhodium(I)-Catalyzed [2+2+2] Cycloaddition Employing a Cleavable Tether

A Coupling of Benzamides and Donor/Acceptor Diazo Compounds To Form gamma-Lactams via Rh(III)-Catalyzed C-H Activation

Enantioselective Synthesis of the Tricyclic Core of FR901483 Featuring a Rhodium-Catalyzed [2+2+2] Cycloaddition

Perfluorinated Taddol phosphoramidite as an L,Z-ligand on Rh(I) and Co(-I): evidence for bidentate coordination via metal-C6F5 interaction

A photoisomerization-coupled asymmetric Stetter reaction: application to the total synthesis of three diastereomers of (-)-cephalimysin A

Asymmetric NHC-Catalyzed Synthesis of a-Fluoroamides From Readily Accessible a-Fluoroenals

Rh(III)-Catalyzed Regioselective Synthesis of Pyridines from Alkenes and alpha,beta-Unsaturated Oxime Esters

Biotinylated Rh(III) Complexes in Engineered Streptavidin for Accelerated Asymmetric C-H Activation

An Asymmetric Synthesis of 1,2,4-Trioxane Anticancer Agents via Desymmetrization of Peroxyquinols through a Bronsted Acid Catalysis Cascade

Exploiting Acyl and Enol Azolium Intermediates via N-Heterocyclic Carbene-Catalyzed Reactions of alpha-Reducible Aldehydes

Catalytic Asymmetric alpha-Acylation of Tertiary Amines Mediated by a Dual Catalysis Mode: N-Heterocyclic Carbene and Photoredox Catalysis

Isolable Analogues of the Breslow Intermediate Derived from Chiral Triazolylidene Carbenes

N-Heterocyclic-Carbene-Catalyzed Asymmetric Oxidative Hetero-Diels-Alder Reactions with Simple Aliphatic Aldehydes

Catalytic Asymmetric Cross-Aza-Benzoin Reactions of Aliphatic Aldehydes with N-Boc-Protected Imines

Catalytic Asymmetric Intermolecular Stetter Reactions of Enolizable Aldehydes with Nitrostyrenes: Computational Study Provides Insight into the Success of the Catalyst

N-Heterocyclic Carbene and Bronsted Acid Cooperative Catalysis: Asymmetric Synthesis of trans-gamma-Lactams

Catalytic Asymmetric Intermolecular Stetter Reaction of Enals with Nitroalkenes: Enhancement of Catalytic Efficiency through Bifunctional Additives

Quantum Mechanical Investigation of the Effect of Catalyst Fluorination in the Intermolecular Asymmetric Stetter Reaction

Enantioselective Rhodium-Catalyzed [4+2] Cycloaddition of alpha,beta-Unsaturated Imines and Isocyanates

Mechanistic Investigation of the Enantioselective Intramolecular Stetter Reaction: Proton Transfer Is the First Irreversible Step

Organocatalytic Hydroacylation of Unactivated Alkenes

Rhodium(III)-catalyzed oxidative carbonylation of benzamides with carbon monoxide

Pyridine synthesis from oximes and alkynes via rhodium(III) catalysis: Cp* and Cp-t provide complementary selectivity

Enamine/carbene cascade catalysis in the diastereo- and enantioselective synthesis of functionalized cyclopentanones

An improved catalyst architecture for rhodium(III) catalyzed C-H activation and its application to pyridone synthesis

Multicatalytic, asymmetric Michael/Stetter reaction of salicylaldehydes and activated alkynes

Stereospecific Polymerization of Chiral Oxazolidinone-Functionalized Alkenes

ORGANOMETALLIC CHEMISTRY C-H carboxylation takes gold

Rhodium-Catalyzed Oxidative Cycloaddition of Benzamides and Alkynes via C-H/N-H Activation

Phosphoramidite-rhodium complexes as catalysts for the asymmetric [2+2+2] cycloaddition of alkenyl isocyanates and alkynes

N-Heterocyclic Carbene Catalyzed Asymmetric Hydration: Direct Synthesis of alpha-Protio and alpha-Deuterio alpha-Chloro and alpha-Fluoro Carboxylic Acids

Excess Substrate is a Spectator Ligand in a Rhodium-Catalyzed Asymmetric [2 + 2 + 2] Cycloaddition of Alkenyl Isocyanates with Tolanes

Enantioselective Rhodium-Catalyzed [2 + 2 + 2] Cycloadditions of Terminal Alkynes and Alkenyl Isocyanates: Mechanistic Insights Lead to a Unified Model that Rationalizes Product Selectivity

Asymmetric Synthesis of Functionalized Cyclopentanones via a Multicatalytic Secondary Amine/N-Heterocyclic Carbene Catalyzed Cascade Sequence

Enantioselective Rhodium-Catalyzed [4+2+2] Cycloaddition of Dienyl Isocyanates for the Synthesis of Bicyclic Azocine Rings

Catalytic Asymmetric Intermolecular Stetter Reaction of Heterocyclic Aldehydes with Nitroalkenes: Backbone Fluorination Improves Selectivity

Predictable and Regioselective Insertion of Internal Unsymmetrical Alkynes in Rhodium-Catalyzed Cycloadditions with Alkenyl Isocyanates

Enantio- and Diastereoselective Intermolecular Stetter Reaction of Glyoxamide and Alkylidene Ketoamides

Regioselective rhodium-catalyzed intermolecular [2+2+2] cycloaddition of alkynes and isocyanates to form pyridones

The Catalytic Asymmetric Intramolecular Stetter Reaction

Ligand differentiated complementary Rh-catalyst systems for the enantioselective desymmetrization of meso-cyclic anhydrides

Enantioselective Rhodium-Catalyzed Alkylative Desymmetrization of 3,5-Dimethylglutaric Anhydride

Total Synthesis of Indolizidine Alkaloid (-)-209D: Overriding Substrate Bias in the Asymmetric Rhodium-Catalyzed [2+2+2] Cycloaddition

Beyond Reppe: Building Substituted Arenes by [2+2+2] Cycloadditions of Alkynes

Carbene Catalysts

Multi-component cycloaddition approaches in the catalytic asymmetric synthesis of alkaloid targets